%nprocs=48
%mem=350GB
%chk=3a-pph3-39-t2-lig.chk
# PBEPBE/def2SVP/W06 int=(grid=ultrafine)
# opt empiricaldispersion=GD3BJ 
# symmetry=none freq=noraman

Title Card Required

0 1
Pd        -0.17627       -1.72051        0.28358
O         -0.59889       -2.99080        1.75377
H          0.26634       -3.32868        2.05784
O          0.32489       -0.41488       -1.32286
O          0.18263       -2.10576       -2.98545
H          0.63851        0.51923       -1.03440
B          0.43224       -0.80103       -2.64498
O          0.79992        0.13911       -3.57755
C          1.77985       -1.84624        0.75208
C          2.75992       -2.07858       -0.21238
C          2.19274       -1.58197        2.09628
C          3.53803       -1.52933        2.43841
C          4.55325       -1.74779        1.46230
C          4.15169       -2.03557        0.10521
C          5.16466       -2.23424       -0.88019
C          6.50930       -2.15137       -0.55019
C          6.90412       -1.86969        0.78710
C          5.94417       -1.67362        1.77005
H          1.42947       -1.39917        2.86934
H          3.83899       -1.30301        3.47429
H          2.48094       -2.28896       -1.25804
H          7.97382       -1.80833        1.03932
H          6.24333       -1.45340        2.80720
H          4.85565       -2.44865       -1.91556
H          7.27701       -2.30288       -1.32446
H         -0.02531       -2.61575       -2.17004
H          0.83833       -0.25703       -4.46533
P         -2.50443       -1.38815       -0.13983
C         -3.44294       -2.87961       -0.66517
C         -2.93825       -4.12321       -0.22856
H         -2.01871       -4.13952        0.38527
C         -3.62893       -5.30256       -0.54885
H         -3.23698       -6.27234       -0.20580
C         -4.81150       -5.24852       -1.30363
H         -5.34576       -6.17647       -1.55942
C         -5.31786       -4.00870       -1.72912
H         -6.24944       -3.96402       -2.31403
C         -4.64106       -2.82359       -1.40585
H         -5.04373       -1.85316       -1.73441
C         -3.45051       -0.80612        1.33144
C         -2.97698       -1.20537        2.59957
H         -2.05522       -1.81604        2.65828
C         -3.68948       -0.83512        3.75203
H         -3.32390       -1.15275        4.74104
C         -4.85896       -0.06485        3.64901
H         -5.40919        0.22925        4.55608
C         -5.33118        0.32632        2.38491
H         -6.25113        0.92492        2.29974
C         -4.63540       -0.04917        1.22642
H         -5.01184        0.25483        0.23768
C         -2.76168       -0.11422       -1.43231
C         -2.69740        1.25406       -1.08645
H         -2.65591        1.55354       -0.02806
C         -2.66826        2.23896       -2.08334
H         -2.60658        3.30023       -1.79947
C         -2.69119        1.87180       -3.43812
H         -2.65407        2.64769       -4.21750
C         -2.74310        0.51465       -3.79049
H         -2.75158        0.21825       -4.85061
C         -2.77688       -0.47531       -2.79651
H         -2.79121       -1.53670       -3.08480
P          1.16192        2.24050       -0.14838
C          0.38320        3.67158       -0.99597
C         -0.32235        4.69269       -0.32973
H         -0.38633        4.68651        0.76888
C         -0.94988        5.71136       -1.06608
H         -1.50353        6.50307       -0.53832
C         -0.86925        5.72350       -2.46775
H         -1.36003        6.52438       -3.04152
C         -0.16759        4.70528       -3.13623
H         -0.11248        4.70251       -4.23566
C          0.44407        3.67604       -2.40804
H          0.94796        2.85023       -2.93638
C          2.95883        2.61459       -0.15892
C          3.50282        3.86558       -0.51145
H          2.83625        4.69461       -0.79485
C          4.89536        4.04703       -0.50757
H          5.31781        5.02540       -0.78415
C          5.74661        2.98689       -0.15544
H          6.83760        3.13361       -0.15962
C          5.20731        1.73700        0.19339
H          5.86307        0.89395        0.46029
C          3.81842        1.54991        0.18793
H          3.39727        0.56702        0.44803
C          0.68393        2.39990        1.61855
C          1.27888        3.34460        2.48101
H          2.07377        4.00577        2.10200
C          0.86720        3.43119        3.81898
H          1.33630        4.16857        4.48838
C         -0.13629        2.57570        4.30540
H         -0.45608        2.64569        5.35643
C         -0.72111        1.62362        3.45598
H         -1.49945        0.94049        3.82724
C         -0.30731        1.52986        2.11846
H         -0.73591        0.74843        1.46771

