%nprocs=48
%mem=350GB
%chk=3a-pph3-43-t3-lig.chk
# PBEPBE/def2SVP/W06 int=(grid=ultrafine)
# opt empiricaldispersion=GD3BJ 
# symmetry=none freq=noraman

Title Card Required

0 1
Pd        -0.21283       -1.54500        0.32234
O         -0.66818       -2.51192        2.01074
H          0.18912       -2.80806        2.37367
O          0.37981       -0.62263       -1.55670
H          0.71121        0.28124       -1.23821
C          1.73625       -1.60661        0.83534
C          2.71635       -2.03499       -0.05968
C          2.14570       -1.12676        2.12014
C          3.48889       -1.04958        2.46363
C          4.50595       -1.46547        1.55598
C          4.10676       -1.98022        0.26671
C          5.12216       -2.37789       -0.65427
C          6.46651       -2.27219       -0.32734
C          6.85806       -1.76532        0.94288
C          5.89549       -1.37258        1.86239
H          1.38327       -0.78830        2.83899
H          3.78624       -0.64830        3.44626
H          2.43464       -2.40162       -1.05990
H          7.92697       -1.68659        1.19386
H          6.19233       -0.97698        2.84684
H          4.81563       -2.76668       -1.63835
H          7.23578       -2.58120       -1.05178
P         -2.52707       -1.29360       -0.15123
C         -3.40491       -2.83986       -0.61264
C         -2.91901       -4.01882       -0.00734
H         -2.05039       -3.94782        0.67277
C         -3.56141       -5.24093       -0.25770
H         -3.18522       -6.16037        0.21633
C         -4.67419       -5.29376       -1.11276
H         -5.16950       -6.25605       -1.31414
C         -5.15968       -4.11822       -1.70993
H         -6.03625       -4.15803       -2.37477
C         -4.53278       -2.88911       -1.45595
H         -4.92149       -1.96788       -1.91702
C         -3.58126       -0.61847        1.19982
C         -3.16321       -0.86269        2.52509
H         -2.21149       -1.40615        2.69180
C         -3.96722       -0.42786        3.59202
H         -3.64684       -0.62401        4.62727
C         -5.17111        0.25133        3.34707
H         -5.79300        0.59506        4.18798
C         -5.58756        0.48652        2.02567
H         -6.53495        1.01190        1.82989
C         -4.80061        0.04569        0.95205
H         -5.13495        0.22326       -0.08181
C         -2.72355       -0.11966       -1.54970
C         -2.73990        1.27259       -1.30113
H         -2.82343        1.64445       -0.26879
C         -2.63385        2.18888       -2.35636
H         -2.63345        3.26755       -2.13984
C         -2.50439        1.73281       -3.67859
H         -2.41178        2.45495       -4.50356
C         -2.48081        0.35362       -3.93915
H         -2.37620       -0.01312       -4.97165
C         -2.58489       -0.56969       -2.88428
H         -2.55588       -1.64972       -3.09725
P          1.17935        2.11418       -0.25370
C          0.28597        3.61087       -0.84749
C         -0.59044        4.35794       -0.03551
H         -0.70152        4.09913        1.02830
C         -1.32095        5.42779       -0.57920
H         -2.00372        6.00233        0.06548
C         -1.17518        5.77173       -1.93241
H         -1.74446        6.61403       -2.35391
C         -0.29651        5.03514       -2.74631
H         -0.17502        5.29854       -3.80827
C          0.41896        3.95561       -2.21166
H          1.09180        3.37073       -2.85932
C          2.95612        2.55628       -0.40001
C          3.44126        3.87203       -0.54339
H          2.73645        4.71545       -0.60169
C          4.82466        4.10213       -0.60835
H          5.20078        5.13058       -0.72253
C          5.72728        3.02867       -0.51984
H          6.81085        3.21725       -0.56663
C          5.24743        1.71656       -0.37432
H          5.94125        0.86516       -0.29917
C          3.86623        1.48085       -0.32491
H          3.48964        0.45236       -0.22018
C          0.89018        2.10086        1.56298
C          1.83958        2.58875        2.48282
H          2.77947        3.02844        2.11768
C          1.59622        2.49772        3.86165
H          2.34831        2.87270        4.57264
C          0.40220        1.92844        4.33287
H          0.21523        1.85533        5.41515
C         -0.54898        1.44319        3.42120
H         -1.48260        0.98332        3.77569
C         -0.30096        1.51555        2.04313
H         -1.02803        1.08210        1.33891
H         -0.42973       -0.39943       -2.06723

