%nprocs=48
%mem=350GB
%chk=3d-pcpt3-43-t3-lig.chk
# PBEPBE/def2SVP/W06 int=(grid=ultrafine)
# opt empiricaldispersion=GD3BJ 
# symmetry=none freq=noraman

Title Card Required

0 1
Pd        -0.02439       -1.27839        0.46088
O         -0.22402       -1.99701        2.31513
H          0.67426       -2.28829        2.56647
O          0.24269       -0.31948       -1.47937
H          0.10218        0.65293       -1.19227
C          1.95254       -0.98806        0.78615
C          2.88264       -1.27037       -0.22029
C          2.44695       -0.41082        2.00017
C          3.78351       -0.06766        2.15186
C          4.72796       -0.29942        1.10802
C          4.26885       -0.94140       -0.09958
C          5.21054       -1.19571       -1.13978
C          6.53925       -0.81812       -1.00851
C          6.98819       -0.17445        0.17695
C          6.09927        0.07452        1.21329
H          1.74154       -0.23044        2.82744
H          4.13473        0.40098        3.08623
H          2.57222       -1.78225       -1.15122
H          8.04412        0.12134        0.27136
H          6.44268        0.56640        2.13734
H          4.85996       -1.69144       -2.05928
H          7.25148       -1.01633       -1.82420
P         -2.27838       -1.84665       -0.02153
C         -2.42490       -3.69310       -0.23650
C         -1.77909       -4.49759        0.94058
C         -0.71393       -5.40421        0.28712
H          0.26602       -4.87936        0.29305
H         -0.57563       -6.36356        0.82509
C         -1.18377       -5.57403       -1.16260
H         -2.02752       -6.29735       -1.21357
H         -0.39276       -5.93892       -1.84938
H         -1.31153       -3.82662        1.69010
H         -2.55798       -5.09916        1.45136
C         -1.67802       -4.16489       -1.51326
H         -2.31045       -4.12412       -2.42254
H         -0.79519       -3.50957       -1.69031
H         -3.50495       -3.93846       -0.32460
C         -3.57303       -1.38040        1.22847
H         -4.57008       -1.61116        0.79235
C         -3.50707        0.13306        1.60291
H         -4.32285        0.69475        1.10486
C         -3.61491        0.19648        3.14741
H         -4.25139        1.03343        3.49866
C         -4.13807       -1.18659        3.56472
H         -5.24112       -1.24038        3.42782
H         -3.92338       -1.43180        4.62460
H         -2.60434        0.34750        3.58008
H         -2.55137        0.58071        1.26449
C         -3.43366       -2.12587        2.57804
H         -3.86539       -3.14561        2.54621
H         -2.35845       -2.21116        2.84194
C         -2.91439       -1.21601       -1.66276
H         -2.15205       -1.59387       -2.37259
C         -4.32188       -1.72403       -2.08036
H         -4.93900       -1.95753       -1.18602
H         -4.27203       -2.65329       -2.68135
C         -4.95851       -0.54345       -2.83175
H         -6.06428       -0.60699       -2.88731
C         -4.44893        0.67485       -2.05074
H         -4.58727        1.63482       -2.58815
H         -5.00133        0.75810       -1.08928
H         -4.57693       -0.50502       -3.87548
C         -2.97032        0.34012       -1.78575
H         -2.34614        0.65785       -2.64576
H         -2.55683        0.86431       -0.90321
P          0.26735        2.61003       -0.35414
C          0.67897        2.64622        1.46271
C         -0.33298        1.94302        2.39025
C          0.14777        2.37742        3.77983
H         -0.59157        2.18118        4.58231
H          1.07130        1.81607        4.04056
C          0.46651        3.87425        3.59791
H          1.19264        4.25467        4.34388
H         -0.46285        4.46762        3.72852
H         -1.36319        2.31814        2.22150
H         -0.35034        0.84357        2.23472
C          0.97981        4.01464        2.13591
H          2.06509        4.23693        2.09431
H          0.47071        4.85498        1.62119
H          1.60081        2.02720        1.50193
C          1.84920        3.28319       -1.09323
H          1.99796        4.30972       -0.69439
C          1.83572        3.33608       -2.64184
H          1.38902        4.26879       -3.03760
C          3.30775        3.14197       -3.03390
H          3.87343        4.08190       -2.85092
C          3.77184        2.04691       -2.06525
H          4.87177        1.96009       -1.96852
H          3.41349        1.05808       -2.42546
H          3.44413        2.87854       -4.10250
H          1.23322        2.49078       -3.04391
C          3.08194        2.39276       -0.72754
H          3.76403        2.94812       -0.05351
H          2.80045        1.47112       -0.18107
C         -0.93830        4.00981       -0.63297
H         -0.42250        4.95606       -0.35817
C         -1.41399        4.10650       -2.11552
H         -1.24126        3.15217       -2.65491
H         -0.83856        4.88083       -2.65892
C         -2.92977        4.44110       -2.05932
H         -3.52243        3.54509       -2.33521
C         -3.21353        4.80885       -0.59298
H         -2.96724        5.87681       -0.40708
H         -4.27334        4.66110       -0.30243
H         -3.21563        5.24360       -2.76791
C         -2.24155        3.91620        0.18948
H         -2.10574        4.22711        1.24410
H         -2.61741        2.86976        0.20162
H          1.22203       -0.36249       -1.56210

