%nprocs=48
%mem=350GB
%chk=3e-pcy3-45-p1-h2o.chk
# PBEPBE/def2SVP/W06 int=(grid=ultrafine)
# opt empiricaldispersion=GD3BJ 
# symmetry=none freq=noraman

Title Card Required

0 1
Pd         0.12543       -0.37640        0.46170
O          0.01108       -2.36532        1.02750
H          0.73963       -2.46855        1.67144
O          1.40808       -3.56168       -1.01185
C          1.96145       -0.48796        1.31120
C          2.97069       -1.27065        0.75343
C          2.21620        0.14536        2.56871
C          3.45844        0.06091        3.18476
C          4.52506       -0.67344        2.59032
C          4.26038       -1.37454        1.35820
C          5.30704       -2.14316        0.76631
C          6.56326       -2.20251        1.35153
C          6.82680       -1.50104        2.56043
C          5.82600       -0.75627        3.16780
H          1.41680        0.71042        3.06767
H          3.63159        0.56372        4.15032
H          2.78910       -1.86093       -0.15910
H          7.82745       -1.55590        3.01579
H          6.02275       -0.21823        4.10894
H          5.09331       -2.68779       -0.16667
H          7.36204       -2.79717        0.88222
H          0.86049       -3.13349       -0.28263
P         -2.33839       -0.85666        0.06439
C         -2.79169       -1.35844        1.81436
C         -2.33955       -0.31260        2.85384
C         -2.49216       -0.86239        4.27799
H         -2.19239       -0.09198        5.01987
C         -3.92472       -1.34136        4.54810
H         -4.61242       -0.46519        4.52331
H         -4.00545       -1.77122        5.56871
C         -4.38109       -2.36403        3.49912
H         -5.43197       -2.67068        3.68619
H         -3.76274       -3.28481        3.59088
H         -1.78820       -1.71450        4.40715
H         -2.93636        0.62131        2.75425
H         -1.28169       -0.03194        2.65223
C         -4.23810       -1.80947        2.07272
H         -4.93596       -0.95239        1.95196
H         -4.55364       -2.57350        1.33258
H         -2.10696       -2.22649        1.94137
C         -3.89938        0.05495       -0.53882
C         -4.36131        1.25469        0.30254
H         -4.44076        0.98155        1.37230
C         -5.70345        1.80900       -0.19761
H         -6.00864        2.67486        0.42728
H         -6.49362        1.03530       -0.06802
C         -5.62329        2.21082       -1.67429
H         -6.60372        2.58781       -2.03374
H         -4.90447        3.05512       -1.78220
C         -5.14949        1.03447       -2.53392
H         -5.92434        0.23534       -2.51931
H         -5.03992        1.34224       -3.59539
H         -3.60346        2.05713        0.23905
H         -4.67966       -0.73539       -0.44365
C         -3.82407        0.45152       -2.02303
H         -3.01879        1.20831       -2.14849
H         -3.53606       -0.41496       -2.65022
C         -2.56473       -2.43186       -0.98110
H         -3.61653       -2.38592       -1.34892
C         -2.38537       -3.76760       -0.23242
H         -3.12081       -3.84914        0.59256
H         -1.38072       -3.77669        0.23427
C         -2.54386       -4.96766       -1.17788
H         -3.59041       -5.00908       -1.56063
H         -2.38295       -5.90640       -0.60709
C         -1.57275       -4.88572       -2.36052
C         -1.78437       -3.57825       -3.13069
H         -2.80233       -3.56809       -3.58416
H         -1.06625       -3.49587       -3.97456
H         -0.52928       -4.90194       -1.97577
H         -1.69619       -5.76089       -3.03262
C         -1.63020       -2.36565       -2.20437
H         -1.79350       -1.42794       -2.77248
H         -0.58880       -2.32406       -1.82469
P          0.63940        1.71992       -0.32788
C          0.01631        3.19226        0.65704
C         -1.51383        3.25737        0.67799
C         -2.03764        4.44286        1.49900
H         -1.74937        5.39223        0.99402
H         -3.14825        4.42328        1.51493
C         -1.47559        4.43493        2.92466
H         -1.82735        5.32440        3.48795
H         -1.86811        3.54399        3.46520
C          0.05607        4.37294        2.90848
H          0.46032        5.30984        2.46274
H          0.45624        4.32150        3.94267
H         -1.92191        3.30924       -0.35215
H         -1.88199        2.30676        1.11789
H          0.40468        4.10003        0.14389
C          0.55387        3.16913        2.09807
H          1.66128        3.11943        2.11419
H          0.19373        2.23414        2.57909
C         -0.12157        1.97999       -2.02085
C          0.13792        3.33099       -2.70661
H         -0.08305        4.17673       -2.02293
C         -0.69896        3.45664       -3.98977
H         -1.77882        3.46912       -3.71670
H         -0.49128        4.42845       -4.48499
C         -0.43411        2.29262       -4.95340
H         -1.07003        2.38681       -5.85849
H          0.62077        2.34733       -5.30560
C         -0.66647        0.93895       -4.26951
H         -1.74650        0.83340       -4.02660
H         -0.42117        0.10463       -4.95966
H          1.21564        3.40890       -2.96685
H         -1.20635        1.92586       -1.77218
C          0.15886        0.81007       -2.98242
H         -0.05131       -0.14786       -2.46549
H          1.23491        0.79363       -3.24826
C          2.48760        2.06081       -0.42646
C          3.19342        1.19135       -1.48249
H          2.83169        0.14610       -1.41952
C          4.71602        1.25062       -1.30529
H          4.98156        0.80012       -0.32415
H          5.21241        0.62661       -2.07784
C          5.22390        2.69573       -1.37141
H          6.31889        2.73284       -1.19235
H          5.06133        3.09456       -2.39876
C          4.49004        3.59165       -0.36603
H          4.74730        3.26633        0.66695
H          4.83171        4.64429       -0.45851
H          2.93580        1.56732       -2.49689
H          2.82162        1.68400        0.56535
C          2.96272        3.52174       -0.53615
H          2.48222        4.16232        0.23008
H          2.68085        3.94504       -1.52404
H          1.25088       -2.97789       -1.77446

