%nprocs=48
%mem=350GB
%chk=3k-phjohnphos-99-lig.chk
# PBEPBE/def2SVP/W06 int=(grid=ultrafine)
# opt empiricaldispersion=GD3BJ 
# symmetry=none freq=noraman

Title Card Required

0 1
P         -0.65482       -0.14272       -0.94191
C         -2.43793       -0.46821       -0.56931
C         -2.90019       -1.36614        0.41448
C         -4.27639       -1.58411        0.58879
H         -4.62096       -2.29119        1.35926
C         -5.20992       -0.90436       -0.20853
H         -6.28799       -1.07492       -0.06662
C         -4.76035       -0.01234       -1.19627
H         -5.48452        0.51821       -1.83353
H         -2.17843       -1.90121        1.04893
C         -3.38611        0.19175       -1.38443
H         -3.03750        0.87418       -2.17683
C         -0.35942        1.44782       -0.01469
C          0.98455        1.89880        0.13270
C          2.12963        1.11092       -0.40936
C          2.26201        0.87477       -1.79477
H          1.52815        1.31037       -2.48836
C          3.31620        0.09121       -2.28639
H          3.40710       -0.08170       -3.36970
C          4.25184       -0.46991       -1.40284
H          5.07257       -1.09331       -1.78928
C          4.13768       -0.22919       -0.02454
H          4.86504       -0.66766        0.67548
C          3.08817        0.55955        0.46686
H          2.98127        0.72639        1.54926
C          1.23497        3.08609        0.84877
H          2.27784        3.41893        0.96693
C          0.18587        3.84599        1.38698
H          0.40389        4.77642        1.93289
C         -1.13674        3.41181        1.22302
H         -1.96979        3.99534        1.64422
C         -1.40336        2.21806        0.53416
H         -2.44228        1.86963        0.43729
C          0.23368       -1.31496        0.18473
C          0.27769       -1.15327        1.58605
H         -0.25802       -0.31220        2.05308
C          1.01660       -2.04216        2.37953
H          1.04631       -1.90618        3.47179
C          1.72576       -3.09823        1.78208
H          2.31366       -3.78951        2.40529
C          1.68886       -3.26484        0.38940
H          2.25095       -4.08423       -0.08421
C          0.94640       -2.37704       -0.40497
H          0.93543       -2.49055       -1.50024

