%nprocs=48
%mem=350GB
%chk=3x-tbubrettphos-62-t3ob-h2o.chk
# PBEPBE/def2SVP/W06 int=(grid=ultrafine)
# opt empiricaldispersion=GD3BJ 
# symmetry=none freq=noraman

Title Card Required

0 1
Pd         1.83409       -0.93810       -0.34270
O          3.11537       -2.62948       -0.64574
B          2.89452       -3.21313        0.55748
O          1.75558       -4.03892        0.74855
O          3.72270       -3.08122        1.66577
O          1.75899       -3.27023       -2.74346
H          2.41969       -3.08713       -1.97307
O          0.18126       -2.43534       -0.82539
H          0.61310       -2.78586       -1.67905
H          0.47459       -3.12605       -0.17346
C          3.46926        0.13100       -0.01014
C          4.08684        0.25904        1.23179
C          4.17239        0.60458       -1.16307
C          5.41595        1.20993       -1.05694
C          6.04857        1.37627        0.20913
C          5.36820        0.87610        1.37791
C          5.99746        1.02175        2.65017
C          7.23759        1.63314        2.76681
C          7.90577        2.12779        1.61375
C          7.32071        2.00003        0.36185
H          3.72856        0.46922       -2.15981
H          5.93633        1.56462       -1.96141
H          3.60612       -0.11758        2.14578
H          8.88936        2.61072        1.71758
H          7.83457        2.37864       -0.53613
H          5.47720        0.63857        3.54262
H          7.70889        1.73731        3.75626
H          1.72506       -4.36259        1.66705
H          4.43740       -2.45884        1.43115
H          1.75550       -4.24207       -2.81411
P          0.27044        0.70369        0.00339
C         -1.06480        0.45300       -1.34302
C         -0.45721        0.26869       -2.63688
C         -1.21406        0.29256       -3.81622
H         -0.72050        0.18159       -4.78906
C         -2.59904        0.44994       -3.76857
H         -3.17160        0.47226       -4.70429
C         -3.23297        0.52307       -2.52504
O         -4.59678        0.56684       -2.39935
C         -5.38623        0.50970       -3.56990
H         -5.19897        1.37602       -4.24379
H         -6.43942        0.53793       -3.23393
H         -5.21320       -0.43168       -4.13929
O          0.88929        0.06591       -2.68678
C          1.51119       -0.25238       -3.92069
H          1.06710       -1.16235       -4.37431
H          2.56543       -0.47524       -3.67714
H          1.46406        0.60069       -4.63378
C         -2.49560        0.50147       -1.29799
C         -3.39889        0.33380       -0.09968
C         -3.69896       -1.00459        0.31090
C         -3.13821       -2.22454       -0.42650
C         -4.07403       -2.63400       -1.58144
H         -3.63813       -3.48178       -2.14888
H         -4.25345       -1.80246       -2.28476
H         -5.06062       -2.95618       -1.18670
H         -2.15827       -1.94477       -0.86119
C         -2.88682       -3.44791        0.46906
H         -2.32594       -4.21404       -0.10269
H         -3.83227       -3.92152        0.80705
H         -2.29138       -3.19792        1.36790
C         -4.58613       -1.20497        1.38150
H         -4.78859       -2.23512        1.70971
C         -5.21682       -0.13926        2.04539
C         -4.98050        1.15530        1.56554
H         -5.50497        1.99762        2.04449
C         -6.11238       -0.37738        3.25175
C         -5.28006       -0.83816        4.46191
H         -4.79498       -1.81578        4.25900
H         -5.91627       -0.95673        5.36333
H         -4.47766       -0.11029        4.69726
H         -6.56972        0.60271        3.51139
C         -7.25478       -1.36038        2.95113
H         -7.92703       -1.46348        3.82751
H         -6.86619       -2.37211        2.71254
H         -7.86156       -1.02176        2.08769
C         -4.10766        1.41610        0.49091
C         -4.02471        2.85063       -0.02781
C         -5.31192        3.23589       -0.78335
H         -6.18467        3.23094       -0.09753
H         -5.51861        2.52698       -1.60375
H         -5.22281        4.25763       -1.20734
H         -3.18736        2.89023       -0.75171
C         -3.76162        3.88924        1.07744
H         -3.55834        4.88386        0.63126
H         -4.64473        4.00443        1.73900
H         -2.90233        3.62080        1.72005
C          0.70873        2.57004       -0.28537
C         -0.55853        3.43193       -0.33935
H         -1.15738        3.37839        0.58439
H         -0.26236        4.49277       -0.48421
H         -1.20260        3.14483       -1.19206
C          1.44562        2.73622       -1.62596
H          1.74551        3.80214       -1.71379
H          2.35860        2.11967       -1.67823
H          0.79833        2.50343       -2.49120
C          1.64028        3.07132        0.83250
H          2.54620        2.44334        0.93181
H          1.13227        3.13306        1.81293
H          1.97007        4.09899        0.57190
C         -0.27197        0.43947        1.84136
C         -0.87106       -0.96826        1.94891
H         -1.08510       -1.17776        3.01849
H         -1.81674       -1.05800        1.39792
H         -0.15999       -1.73322        1.58373
C         -1.24158        1.47779        2.41311
H         -0.79245        2.48795        2.46760
H         -1.50329        1.18144        3.45130
H         -2.18407        1.52677        1.84335
C          1.01411        0.40887        2.69360
H          0.70978        0.24275        3.74856
H          1.65667       -0.43712        2.38432
H          1.61216        1.33407        2.65679

