%nprocs=48
%mem=350GB
%chk=9e-pcbu3-43-t3-lig.chk
# PBEPBE/def2SVP/W06 int=(grid=ultrafine)
# opt empiricaldispersion=GD3BJ 
# symmetry=none freq=noraman

Title Card Required

0 1
Pd        -0.32192       -1.19695        0.65656
O         -0.00726       -1.99427        2.45372
H          0.92022       -2.30139        2.42614
O         -0.49863       -0.27583       -1.31848
H         -0.30318        0.71522       -1.16059
C          1.66525       -1.25572        0.31337
C          2.59744       -0.71267        1.19837
C          2.15640       -1.79799       -0.92086
C          3.50458       -1.75171       -1.25682
C          4.45441       -1.14917       -0.38186
C          3.98716       -0.62680        0.88054
C          4.92988       -0.00632        1.75377
C          6.26732        0.09971        1.40100
C          6.72591       -0.41713        0.15789
C          5.83634       -1.03109       -0.71175
H          1.45984       -2.30150       -1.61610
H          3.85853       -2.18319       -2.20764
H          2.26430       -0.30912        2.16895
H          7.78956       -0.32888       -0.11089
H          6.18556       -1.43305       -1.67625
H          4.57121        0.39351        2.71557
H          6.98092        0.58372        2.08548
P         -2.67257       -1.34353        1.06833
C         -3.27066       -3.09634        0.98341
C         -2.37963       -4.10544        1.77581
H         -2.98332       -4.83156        2.35573
C         -1.83836       -4.66188        0.43234
H         -1.87490       -5.76073        0.29447
H         -0.80546       -4.31334        0.22953
H         -1.60766       -3.64747        2.42655
H         -4.35175       -3.10166        1.24076
C         -2.89862       -3.83497       -0.33947
H         -3.74209       -4.43940       -0.72949
H         -2.51540       -3.20366       -1.16620
C         -3.29422       -0.76677        2.71527
C         -2.59456       -1.25432        4.01770
H         -3.08635       -2.08249        4.56605
H         -1.53825       -1.52255        3.81284
C         -2.73247        0.18268        4.58389
H         -3.63934        0.30577        5.21122
H         -1.86452        0.59696        5.13577
H         -4.39134       -0.94951        2.74832
C         -2.95953        0.69216        3.13807
H         -3.73413        1.46608        2.96351
H         -2.01129        1.02633        2.67307
C         -3.84266       -0.45210       -0.06152
C         -3.74261       -0.63677       -1.60404
H         -2.71727       -0.91675       -1.91102
C         -3.97368        0.88829       -1.76620
H         -3.34774        1.41834       -2.51272
H         -5.03636        1.13605       -1.96370
H         -4.46824       -1.32943       -2.07425
C         -3.60462        1.07015       -0.27168
H         -2.53230        1.32287       -0.13789
H         -4.20705        1.77159        0.33938
H         -4.87802       -0.64540        0.29454
P          0.38464        2.73215       -1.01883
C         -0.60711        4.02901       -1.90384
C         -2.05439        4.34544       -1.42826
H         -2.19176        5.23459       -0.78158
C         -2.48283        4.43856       -2.91569
H         -2.46077        5.48249       -3.28846
H         -3.45539        3.98675       -3.19637
H         -2.51871        3.47413       -0.92611
H         -0.00280        4.96077       -1.96251
C         -1.19527        3.66398       -3.29766
H         -0.62896        3.98861       -4.19301
H         -1.38037        2.57199       -3.37888
C          0.73418        3.55851        0.61052
C         -0.40608        3.32706        1.65020
H         -0.49995        4.19539        2.33375
H         -1.41751        3.07995        1.26713
C          0.43057        2.17638        2.26338
H          0.46209        2.09054        3.36748
H          0.14117        1.18514        1.84723
H          1.02575        4.61335        0.41552
C          1.67861        2.73603        1.53917
H          2.27740        3.41306        2.18190
H          2.36371        2.00245        1.07279
C          1.99992        2.86142       -1.92446
C          2.04920        2.25485       -3.35885
H          1.30112        1.44242       -3.48012
C          3.45950        1.69591       -3.03661
H          3.69183        0.66438       -3.36893
H          4.26235        2.37072       -3.39610
H          1.93803        2.95314       -4.21234
C          3.15610        1.89672       -1.53193
H          2.77061        0.96677       -1.07089
H          3.95868        2.29307       -0.88023
H          2.33850        3.92049       -1.92777
H          0.33443       -0.58201       -1.73909

