%nprocs=48
%mem=350GB
%chk=2g-pcy3-43-t3-lig.chk
# PBEPBE/def2SVP/W06 int=(grid=ultrafine)
# opt empiricaldispersion=GD3BJ 
# symmetry=none freq=noraman

Title Card Required

0 1
Pd        -1.42043       -0.78483        0.19177
O         -2.77464       -1.34375        1.55315
H         -2.65710       -2.31136        1.61717
O         -0.01861       -0.13549       -1.33880
H          0.92239       -0.01775       -0.93341
C         -0.20558       -2.31155        0.76825
C          0.71704       -2.92286       -0.08258
C         -0.21418       -2.74045        2.13725
C          0.68539       -3.68074        2.61991
C          1.65931       -4.27278        1.76389
C          1.65672       -3.89811        0.37003
C          2.61023       -4.50475       -0.50120
C          3.53989       -5.41739       -0.02246
C          3.55393       -5.77015        1.35502
C          2.62799       -5.21145        2.22505
H         -0.94610       -2.28497        2.82408
H          0.66983       -3.97052        3.68371
H          0.76846       -2.66501       -1.15573
H          4.29603       -6.49322        1.72628
H          2.62726       -5.48781        3.29159
H          2.59629       -4.23156       -1.56876
H          4.26898       -5.87353       -0.71003
P         -3.01039        0.93160       -0.23361
C         -4.56552        0.22267       -1.03774
C         -4.15704       -0.91523       -1.99964
C         -5.36792       -1.54308       -2.70085
H         -5.03198       -2.36397       -3.36909
C         -6.39070       -2.05883       -1.68289
H         -5.93554       -2.89252       -1.10282
H         -7.27958       -2.48051       -2.19800
C         -6.80567       -0.94412       -0.71685
H         -7.51210       -1.33297        0.04673
H         -7.35912       -0.16009       -1.28287
H         -5.85150       -0.78335       -3.35679
H         -3.62536       -1.68685       -1.39865
H         -3.42148       -0.55544       -2.74713
C         -5.59571       -0.30441       -0.02060
H         -5.08169       -1.04477        0.63124
H         -5.94840        0.51385        0.63888
H         -5.03312        1.04689       -1.62620
C         -3.58353        1.63960        1.40039
C         -2.42936        1.83197        2.40216
H         -1.85020        0.88882        2.46245
C         -2.97230        2.22621        3.78167
H         -2.13129        2.39065        4.48877
H         -3.56076        1.37452        4.19013
C         -3.86458        3.47206        3.70689
H         -4.27170        3.72276        4.70918
H         -3.24691        4.34472        3.39370
C         -5.00632        3.28155        2.69968
H         -5.68597        2.47917        3.06506
H         -5.62085        4.20386        2.62626
H         -1.73285        2.62118        2.04431
H         -4.18141        0.79414        1.80221
C         -4.47368        2.88847        1.31274
H         -3.88410        3.73763        0.90029
H         -5.31753        2.72467        0.60881
C         -2.61027        2.41276       -1.31504
H         -3.48705        3.09783       -1.25119
C         -2.41778        2.02043       -2.79247
H         -3.33453        1.53996       -3.18914
H         -1.60099        1.26851       -2.85367
C         -2.06370        3.23789       -3.65861
H         -2.92297        3.94623       -3.66203
H         -1.91696        2.92077       -4.71273
C         -0.81715        3.95763       -3.13388
C         -0.99208        4.35479       -1.66411
H         -1.79294        5.12441       -1.58615
H         -0.06623        4.83125       -1.27605
H          0.05698        3.27611       -3.22502
H         -0.58781        4.84950       -3.75456
C         -1.36419        3.14964       -0.78865
H         -1.52346        3.48297        0.25619
H         -0.51919        2.42855       -0.76231
P          2.81490        0.38758       -0.13440
C          2.66161        0.71077        1.70431
C          1.39094        1.55426        1.94249
C          1.12322        1.77513        3.43582
H          1.95276        2.37133        3.88000
H          0.19939        2.37546        3.56752
C          1.00722        0.43353        4.16705
H          0.80764        0.59104        5.24782
H          0.13570       -0.12446        3.75805
C          2.27618       -0.40306        3.96913
H          3.13284        0.10919        4.46401
H          2.17199       -1.39241        4.46236
H          1.46352        2.52794        1.41187
H          0.51936        1.01892        1.49816
H          3.54772        1.28704        2.05132
C          2.59490       -0.61514        2.48307
H          3.54845       -1.17262        2.38607
H          1.80905       -1.25564        2.03492
C          3.55519        1.95977       -0.87533
C          2.47218        2.73454       -1.65164
H          1.95013        2.05407       -2.35614
C          3.05235        3.94811       -2.38835
H          3.74789        3.59245       -3.18204
H          2.24189        4.50093       -2.90839
C          3.81123        4.87410       -1.43019
H          4.25837        5.72650       -1.98338
H          3.09057        5.31580       -0.70488
C          4.89237        4.10743       -0.65848
H          5.67032        3.75333       -1.37217
H          5.40988        4.77879        0.05884
H          1.69343        3.07825       -0.93505
H          4.29027        1.57896       -1.62230
C          4.30583        2.89773        0.08566
H          5.10734        2.35128        0.62236
H          3.60095        3.26389        0.86412
C          4.17950       -0.88326       -0.30516
C          4.33969       -1.29773       -1.78099
H          3.35791       -1.62223       -2.18771
C          5.38348       -2.41251       -1.94622
H          5.00197       -3.33212       -1.45247
H          5.50970       -2.65695       -3.02212
C          6.72897       -2.03165       -1.31679
H          7.45165       -2.86852       -1.41670
H          7.16779       -1.17152       -1.87234
C          6.55698       -1.64263        0.15643
H          6.20576       -2.52837        0.73174
H          7.53069       -1.34410        0.59898
H          4.65240       -0.41527       -2.38520
H          3.77224       -1.76672        0.23706
C          5.53556       -0.50631        0.31385
H          5.41483       -0.24230        1.38505
H          5.92974        0.40247       -0.19339
H          0.08929       -0.90306       -1.93376

