%nprocs=48
%mem=350GB
%chk=3i-xphos-20-ts-t3-t4.chk
# PBEPBE/def2SVP/W06 int=(grid=ultrafine)
# opt=(calcfc,ts,noeigentest) empiricaldispersion=GD3BJ 
# symmetry=none freq=noraman

Title Card Required

0 1
Pd         0.68291        0.43663        0.03450
O          1.18544        1.83953        1.37042
H          2.15367        1.72878        1.45147
O          0.57086       -1.09849       -1.41582
H          1.74856       -0.90000       -0.85902
H          0.21238       -1.86318       -0.91023
C          2.75318       -0.27613       -0.19164
C          3.54510        0.50739       -1.03900
C          3.35927       -0.82806        0.98504
C          4.68976       -0.58933        1.28831
C          5.50472        0.21211        0.43187
C          4.91816        0.77033       -0.76435
C          5.72781        1.57257       -1.62237
C          7.05820        1.81849       -1.31849
C          7.63518        1.26867       -0.14113
C          6.87480        0.48335        0.71396
H          2.74651       -1.44351        1.66019
H          5.14138       -1.01423        2.19923
H          3.10342        0.93842       -1.95332
H          8.69227        1.46939        0.09102
H          7.32169        0.05795        1.62629
H          5.27311        1.99516       -2.53213
H          7.67255        2.43986       -1.98760
P         -1.44797        1.28554       -0.10803
C         -2.01136        0.92317       -1.86112
C         -3.44698        1.32982       -2.22526
C         -3.82767        0.78800       -3.61341
H         -4.85355        1.11992       -3.87910
H         -3.86198       -0.32357       -3.56169
C         -2.82517        1.20959       -4.69440
H         -3.10075        0.76078       -5.67198
H         -2.88028        2.31355       -4.83101
C         -1.39254        0.82411       -4.30570
H         -1.29840       -0.28388       -4.27072
H         -0.67220        1.17525       -5.07404
H         -4.16791        0.95671       -1.47070
H         -3.52777        2.44045       -2.22532
H         -1.95149       -0.18787       -1.84999
C         -1.01377        1.39772       -2.93402
H         -1.03130        2.50729       -2.99251
H          0.01420        1.09737       -2.64864
C         -1.54577        3.12330        0.22879
C         -1.47477        3.38352        1.75085
C         -1.51928        4.88537        2.06049
H         -1.44747        5.04086        3.15766
H         -2.50605        5.30097        1.74997
C         -0.40176        5.64291        1.33465
H         -0.46410        6.73117        1.54755
H          0.58074        5.29507        1.72290
C         -0.46089        5.38413       -0.17464
H         -1.39894        5.82353       -0.58612
H          0.37646        5.89857       -0.69168
H         -2.29898        2.86437        2.27963
H         -0.51989        2.94613        2.11325
H         -2.52216        3.48579       -0.17091
C         -0.41238        3.88323       -0.49213
H          0.54852        3.44973       -0.14128
H         -0.46843        3.72915       -1.58698
C         -2.86331        0.59452        0.87943
C         -4.01734        1.39359        1.05716
C         -5.13838        0.92448        1.75257
H         -6.01835        1.57397        1.87364
C         -5.12800       -0.37076        2.28833
H         -5.99899       -0.75458        2.84067
C         -3.99594       -1.17559        2.11670
H         -3.97688       -2.19284        2.53581
H         -4.04487        2.41003        0.64020
C         -2.85476       -0.71996        1.41771
C         -1.70025       -1.66745        1.29879
C         -0.68146       -1.66153        2.29022
C         -0.75424       -0.72163        3.49073
C         -1.44940       -1.43861        4.66488
H         -0.85469       -2.31618        4.99430
H         -1.55630       -0.75445        5.53162
H         -2.45920       -1.80144        4.38919
H         -1.39205        0.13731        3.19505
C          0.60110       -0.14403        3.91807
H          1.31223       -0.93390        4.23863
H          1.04392        0.45197        3.09379
H          0.46018        0.53119        4.78687
C          0.35463       -2.60920        2.19293
H          1.14395       -2.61735        2.96063
C          0.41685       -3.55236        1.15478
C         -0.61665       -3.55081        0.19883
H         -0.59762       -4.29373       -0.61326
C          1.56869       -4.54267        1.06175
H          2.24592       -4.32595        1.91696
C          1.08037       -5.99358        1.20984
H          0.52034       -6.13711        2.15552
H          0.40704       -6.27704        0.37423
H          1.93531       -6.70044        1.20275
C          2.37786       -4.35028       -0.23254
H          2.76821       -3.31699       -0.31698
H          1.75536       -4.54820       -1.12974
H          3.24025       -5.04730       -0.26406
C         -1.67840       -2.62602        0.24987
C         -2.79323       -2.69468       -0.79166
H         -3.31091       -1.71229       -0.78091
C         -3.83309       -3.76192       -0.40304
H         -3.36403       -4.76688       -0.36009
H         -4.27913       -3.55526        0.58910
H         -4.65538       -3.79974       -1.14701
C         -2.27725       -2.93463       -2.22014
H         -3.10134       -2.81022       -2.95192
H         -1.88545       -3.96483       -2.34803
H         -1.46305       -2.23057       -2.48559

