%nprocs=48
%mem=350GB
%chk=2e-pipr3-43-t3-lig.chk
# PBEPBE/def2SVP/W06 int=(grid=ultrafine)
# opt empiricaldispersion=GD3BJ 
# symmetry=none freq=noraman

Title Card Required

0 1
Pd        -1.10618       -0.75597        0.31701
O         -1.90792       -1.68774        1.89115
H         -1.38129       -2.50605        1.97942
O         -0.19323        0.28761       -1.36036
H          0.41969        0.96903       -0.89376
C          0.62862       -1.77485        0.56090
C          1.34971       -2.25028       -0.53827
C          1.21921       -1.94146        1.85558
C          2.49616       -2.46203        2.01401
C          3.26714       -2.87919        0.88820
C          2.66396       -2.79847       -0.42018
C          3.41792       -3.23658       -1.54893
C          4.71490       -3.70781       -1.40328
C          5.31420       -3.77188       -0.11554
C          4.60034       -3.36997        1.00507
H          0.64679       -1.62702        2.74272
H          2.94031       -2.55111        3.01940
H          0.91617       -2.22912       -1.55768
H          6.34368       -4.14667       -0.01021
H          5.05567       -3.42631        2.00677
H          2.95388       -3.18170       -2.54695
H          5.28514       -4.03402       -2.28666
P         -3.24445        0.24043        0.07117
C         -4.43382       -1.06153       -0.61697
C         -4.97456       -1.98104        0.48689
H         -5.52097       -2.83192        0.02890
H         -5.67781       -1.46597        1.16958
H         -4.13096       -2.38226        1.08754
C         -3.70797       -1.90707       -1.67754
H         -2.89658       -2.49484       -1.20025
H         -4.41983       -2.61594       -2.15086
H         -3.24496       -1.30173       -2.47890
H         -5.27553       -0.50991       -1.09436
C         -3.53028        1.72628       -1.05134
C         -3.27985        1.39597       -2.52895
H         -3.99058        0.64421       -2.92187
H         -3.40319        2.31508       -3.14013
H         -2.24703        1.02228       -2.68070
C         -2.65842        2.90978       -0.61413
H         -2.88571        3.24947        0.41398
H         -1.58250        2.64430       -0.65595
H         -2.81746        3.77322       -1.29412
H         -4.60148        2.00012       -0.92598
C         -3.97772        0.70717        1.73577
C         -5.33529        1.41013        1.65990
H         -5.24141        2.44057        1.25815
H         -6.06203        0.86571        1.02313
H         -5.78137        1.49764        2.67315
C         -2.97209        1.44492        2.62859
H         -2.00902        0.89994        2.65777
H         -3.36505        1.50332        3.66538
H         -2.78294        2.48396        2.29201
H         -4.10086       -0.29879        2.18659
P          1.89897        2.05905        0.12623
C          1.50282        2.62688        1.87139
C          1.18699        1.41241        2.75241
H          0.86303        1.74696        3.76008
H          0.36448        0.80858        2.31262
H          2.05626        0.73961        2.88259
C          0.31701        3.60039        1.84633
H         -0.58477        3.10504        1.43599
H          0.51479        4.50603        1.23985
H          0.07503        3.93413        2.87713
H          2.39717        3.15282        2.27154
C          3.35210        0.88028        0.32359
C          3.83241        0.41160       -1.05594
H          2.99124        0.07172       -1.69282
H          4.37350        1.21440       -1.60034
H          4.52546       -0.44757       -0.94961
H          2.86819        0.00911        0.81705
C          4.51926        1.34981        1.19627
H          4.19294        1.69114        2.19875
H          5.08154        2.17812        0.71808
H          5.23431        0.51367        1.34791
C          2.60149        3.57062       -0.76548
H          3.35159        3.11610       -1.45019
C          1.50739        4.20748       -1.63755
H          1.93069        5.01321       -2.27398
H          0.70446        4.66042       -1.01984
H          1.02866        3.45874       -2.29993
C          3.31756        4.60839        0.10657
H          2.61523        5.12040        0.79502
H          4.12428        4.16301        0.71942
H          3.77519        5.39391       -0.53163
H          0.45920       -0.37893       -1.66752

