%nprocs=48
%mem=350GB
%chk=2e-pipr3-84-lig.chk
# PBEPBE/def2SVP/W06 int=(grid=ultrafine)
# opt empiricaldispersion=GD3BJ 
# symmetry=none freq=noraman

Title Card Required

0 1
C          1.70780       -0.66579       -0.08717
H          1.73285       -1.71438       -0.45928
C          2.82300        0.09960       -0.81292
H          3.81743       -0.33544       -0.57826
H          2.68534        0.07611       -1.91264
H          2.85524        1.16556       -0.50141
C          1.92917       -0.68479        1.42776
H          1.13047       -1.23233        1.96763
H          2.89432       -1.17720        1.67546
H          1.97678        0.34298        1.84252
P          0.02679       -0.06229       -0.72594
C         -1.18531       -1.15268        0.23189
C         -0.89708       -2.63433       -0.04238
H          0.07426       -2.96295        0.37752
H         -1.68549       -3.27198        0.41079
H         -0.88437       -2.84505       -1.13304
H         -1.07415       -0.96430        1.32180
C         -2.61642       -0.79104       -0.19097
H         -2.75889       -0.95211       -1.27995
H         -3.35552       -1.42308        0.34595
H         -2.86646        0.26731        0.02251
C         -0.13654        1.64121        0.11635
H          0.91712        2.00048        0.13909
C         -0.92459        2.58708       -0.80355
H         -1.98479        2.27066       -0.89609
H         -0.92233        3.62351       -0.40288
H         -0.49911        2.60890       -1.82635
C         -0.68151        1.67903        1.54874
H         -0.63448        2.71474        1.94882
H         -1.74523        1.36795        1.59076
H         -0.11472        1.02874        2.24132

